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Air is liquefied by the Linde process, in which air is alternately compressed, cooled, and expanded, each expansion results in a considerable reduction in temperature. With the lower temperature the molecules move more slowly and occupy less space, so the air changes phase to become liquid.
In materials science, liquefaction [1] is a process that generates a liquid from a solid or a gas [2] or that generates a non-liquid phase which behaves in accordance with fluid dynamics. [3] It occurs both naturally and artificially. As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to ...
Liquid oxygen has a clear cyan color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. [2] Liquid oxygen has a density of 1.141 kg/L (1.141 g/ml), slightly denser than liquid water, and is cryogenic with a freezing point of 54.36 K (−218.79 °C; −361.82 °F) and a boiling point of 90.19 K (−182.96 °C; −297.33 °F) at 1 bar (14.5 psi).
The heat exchanger arrangement permits an absolute temperature difference (e.g. 0.27 °C/atm J–T cooling for air) to go beyond a single stage of cooling and can reach the low temperatures required to liquefy "fixed" gases. The Hampson–Linde cycle differs from the Siemens cycle only in the expansion step.
The air is either supplied from diving cylinders or pumped through a hose from the diver's ship on the surface. Submarines use ballast tanks and trim tanks with air to regulate their buoyancy, essentially making them underwater "airships". Bathyscaphes are a type of deep-sea submersibles that use gasoline as the "lifting gas".
Methods of oxygen storage for subsequent use span many approaches, including high pressures in oxygen tanks, cryogenics, oxygen-rich compounds and reaction mixtures, and chemical compounds that reversibly release oxygen upon heating or pressure change. O 2 is the second most important industrial gas.
Various governmental agencies involved with environmental protection and with occupational safety and health have promulgated regulations limiting the allowable concentrations of gaseous pollutants in the ambient air or in emissions to the ambient air. Such regulations involve a number of different expressions of concentration.
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.