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Carbonation is the chemical reaction of carbon dioxide to give carbonates, bicarbonates, and carbonic acid. [1] In chemistry , the term is sometimes used in place of carboxylation , which refers to the formation of carboxylic acids .
The carbon dioxide in the air reacts with the alkali in the cement and makes the pore water more acidic, thus lowering the pH. Carbon dioxide will start to carbonatate the cement in the concrete from the moment the object is made. This carbonatation process will start at the surface, then slowly moves deeper and deeper into the concrete.
Ice will simply expand out of a straight open fracture before it can generate significant pressure. Thus, frost wedging can only take place in small tortuous fractures. [5] The rock must also be almost completely saturated with water, or the ice will simply expand into the air spaces in the unsaturated rock without generating much pressure.
The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3 pm, noticeably shorter than the roughly 140 pm length of a typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls. [19]
The ice crystal growth weakens the rocks which, in time, break up. [3] It is caused by the expansion of ice when water freezes, putting considerable stress on the walls of containment. This is actually a very common process in all humid, temperate areas where there is exposed rock, especially porous rocks like sandstone .
Under 0.3 GPa pressure, carbon dioxide is stable at room temperature in the same form as dry ice. Over 0.5 GPa carbon dioxide forms a number of different solid forms containing molecules. At pressures over 40 GPa and high temperatures, carbon dioxide forms a covalent solid that contains CO 4 tetrahedra, and has the same structure as β-cristobalite
A series of processes that involve carbonization. [2]Carbonization is a pyrolytic reaction, therefore, is considered a complex process in which many reactions take place concurrently such as dehydrogenation, condensation, hydrogen transfer and isomerization.
Enhanced weathering, also termed ocean alkalinity enhancement when proposed for carbon credit systems, is a process that aims to accelerate the natural weathering by spreading finely ground silicate rock, such as basalt, onto surfaces which speeds up chemical reactions between rocks, water, and air.