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Ruthenium(III) acetate, commonly known as basic ruthenium acetate, [1] describes a family of salts where the cation has the formula [Ru 3 O(O 2 CCH 3) 6 (OH 2) 3] +.A representative derivative is the dihydrate of the tetrafluoroborate salt [Ru 3 O(O 2 CCH 3) 6 (OH 2) 3]BF 4 (H 2 O) 2, which is the source of the data in the table above. [2]
Ruthenium(III) acetylacetonate is a coordination complex with the formula Ru(O 2 C 5 H 7) 3. O 2 C 5 H 7 − is the ligand called acetylacetonate . This compound exists as a dark red solid that is soluble in most organic solvents. [ 3 ]
Ruthenium trichloride. The highest known ruthenium halide is the hexafluoride, a dark brown solid that melts at 54 °C.It hydrolyzes violently upon contact with water and easily disproportionates to form a mixture of lower ruthenium fluorides, releasing fluorine gas.
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Diruthenium tetraacetate chloride is the coordination polymer with the formula {[Ru 2 (O 2 CCH 3) 4]Cl} n. A red brown solid, the compound is obtained by the reduction of ruthenium trichloride in acetic acid. [1] The compound has attracted much academic interest because it features a fractional metal-metal bond order of 2.5. [2]
Ruthenium is a chemical element; it has symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the ...
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The most important reagents for the introduction of ruthenium are ruthenium(III) chloride and triruthenium dodecacarbonyl. In its organometallic compounds, ruthenium is known to adopt oxidation states from -2 ([Ru(CO) 4] 2−) to +6 ([RuN(Me)4] −). Most common are those in the 2+ oxidation state, as illustrated below.