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A nuclide is a species of an atom with a specific number of protons and neutrons in the nucleus, for example, carbon-13 with 6 protons and 7 neutrons. The nuclide concept (referring to individual nuclear species) emphasizes nuclear properties over chemical properties, whereas the isotope concept (grouping all atoms of each element) emphasizes chemical over nuclear.
Certain isotopes can signify distinct primary producers forming the bases of food webs and trophic level positioning. The stable isotope compositions are expressed in terms of delta values (δ) in permil (‰), i.e. parts per thousand differences from a standard. They express the proportion of an isotope that is in a sample. The values are ...
Example of six stable isotopocules of ethanol (i.e. with stable isotopes) out of the total number of 288 stable isotopocules Isotopocules are isotopically substituted molecules , which differ only in their isotopic composition or their isotopes' intramolecular position. [ 1 ] "
Isotope fractionation occurs during a phase transition, when the ratio of light to heavy isotopes in the involved molecules changes. When water vapor condenses (an equilibrium fractionation), the heavier water isotopes (18 O and 2 H) become enriched in the liquid phase while the lighter isotopes (16 O and 1 H) tend toward the vapor phase. [1]
Kinetic isotope effect, effect of isotopic substitution on chemical reaction rates; Magnetic isotope effect, when a chemical reaction involves spin-selective processes, such as the radical pair mechanism; Superconductive transition temperature varying by isotope atomic weight: see BCS theory#Underlying evidence
If the definition refers only to one isotope (as that of the dalton does) or to a specific isotope ratio, e.g. Vienna Standard Mean Ocean Water, this removes a source of ambiguity and variation, but adds layers of technical difficulty (preparing samples of a desired isotopic ratio) and uncertainty (regarding how much an actual reference sample ...
An example is water, whose hydrogen-related isotopologues are: "light water" (HOH or H 2 O), "semi-heavy water" with the deuterium isotope in equal proportion to protium (HDO or 1 H 2 HO), "heavy water" with two deuterium atoms (D 2 O or 2 H 2 O); and "super-heavy water" or tritiated water (T 2 O or 3 H 2 O, as well as HTO [1 H 3 HO] and DTO [2 ...
Natural isotopes are either stable isotopes or radioactive isotopes that have a sufficiently long half-life to allow them to exist in substantial concentrations in the Earth (such as bismuth-209, with a half-life of 1.9 × 10 19 years, potassium-40 with a half-life of 1.251(3) × 10 9 years), daughter products of those isotopes (such as 234 Th, with a half-life of 24 days) or cosmogenic ...