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In chemistry a donor number (DN) is a quantitative measure of Lewis basicity.A donor number is defined as the negative enthalpy value for the 1:1 adduct formation between a Lewis base and the standard Lewis acid SbCl 5 (antimony pentachloride), in dilute solution in the noncoordinating solvent 1,2-dichloroethane with a zero DN.
Alternatively, one can graph the expressions and see where they intersect with the line given by the inverse Damköhler number to see the solution for conversion. In the plot below, the y-axis is the inverse Damköhler number and the x-axis the conversion. The rule-of-thumb inverse Damköhler numbers have been placed as dashed horizontal lines.
Parts-per notation is often used describing dilute solutions in chemistry, for instance, the relative abundance of dissolved minerals or pollutants in water.The quantity "1 ppm" can be used for a mass fraction if a water-borne pollutant is present at one-millionth of a gram per gram of sample solution.
For hydrocarbons, the DBE (or IHD) tells us the number of rings and/or extra bonds in a non-saturated structure, which equals the number of hydrogen pairs that are required to make the structure saturated, simply because joining two elements to form a ring or adding one extra bond (e.g., a single bond changed to a double bond) in a structure reduces the need for two H's.
The dissociation constant can be used to calculate the extent of dissociation and hence, make the necessary correction needed to calculate activity coefficients. [17] Ions are spherical, not point charges and are not polarized. Many ions such as the nitrate ion, NO 3 −, are not spherical. Polyatomic ions are also polarizable. Role of the solvent.
The cation transport number of the leading solution is then calculated as t + = z + c L A F I Δ t {\displaystyle t_{+}={\frac {z_{+}cLAF}{I\Delta t}}} where z + {\displaystyle z_{+}} is the cation charge, c the concentration, L the distance moved by the boundary in time Δ t , A the cross-sectional area, F the Faraday constant , and I the ...
where denotes the number of moles of the reactant or product and is the stoichiometric number [4] of the reactant or product. Although less common, we see from this expression that since the stoichiometric number can either be considered to be dimensionless or to have units of moles, conversely the extent of reaction can either be considered to ...
where Q is the ion charge, n is the drift gas number density, μ is the reduced mass of the ion and the drift gas molecules, k is Boltzmann constant, T is the drift gas temperature, and σ is the collision cross section between the ion and the drift gas molecules.