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Trimethyl phosphate is prepared by treating phosphorus oxychloride with methanol in the presence of an amine base: POCl 3 + 3 CH 3 OH + 3 R 3 N → PO(OCH 3 ) 3 + 3 R 3 NH + Cl − It is a tetrahedral molecule that is a weakly polar solvent.
Trimethyl phosphite is an organophosphorus compound with the formula P(OCH 3) 3, often abbreviated P(OMe) 3.It is a colorless liquid with a highly pungent odor. It is the simplest phosphite ester and finds used as a ligand in organometallic chemistry and as a reagent in organic synthesis.
Tris(trimethylsilyl)phosphine is prepared by treating trimethylsilyl chloride, white phosphorus, and sodium-potassium alloy: [2] 1/4 P 4 + 3 Me 3 SiCl + 3 K → P(SiMe 3) 3 + 3 KCl
Melting point: 58 °C (136 °F; 331 K) Boiling point: 289 °C (552 °F; 562 K) Hazards NFPA 704 (fire diamond) 3. Flash point: 172 °C (342 °F; 445 K)
Trimethylsilanol is a weak acid with a pK a value of 11. [10] The acidity is comparable to that of orthosilicic acid, but much higher than the one of alcohols like tert-butanol (pK a 19 [10]). Deprotonation with sodium hydroxide gives sodium trimethylsiloxide. TMS reacts with the silanol groups (R 3 SiOH) giving silyl ethers.
Triphenylmethanol features three phenyl (Ph) rings and an alcohol group bound to a central tetrahedral carbon atom. All three C–Ph bonds are typical of sp 3-sp 2 carbon-carbon bonds with lengths of approximately 1.47 Å, while the C–O bond length is approximately 1.42 Å.
Triethyl phosphite (TEP) is an organophosphorus compound, specifically a phosphite ester, with the formula P(OCH 2 CH 3) 3, often abbreviated P(OEt) 3.It is a colorless, malodorous liquid.
Dimethyl methylphosphonate can be prepared from trimethyl phosphite and a halomethane (e.g. iodomethane) via the Michaelis–Arbuzov reaction. [2]Dimethyl methylphosphonate is a schedule 2 chemical as it may be used in the production of chemical weapons.