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A Newman projection is a drawing that helps visualize the 3-dimensional structure of a molecule. [1] This projection most commonly sights down a carbon-carbon bond, making it a very useful way to visualize the stereochemistry of alkanes.
English: Newman projections of ethane conformations & their relative energy differences (not total energies). Conformations form when ethane rotates about one of its single covalent bond. Torsional/dihedral angle is shown on x-axis. Conformations (according to IUPAC): A: staggered B: eclipsed
In the example of ethane, such a graph shows that rotation around the carbon-carbon bond is not entirely free but that an energy barrier exists. The ethane molecule in the eclipsed conformation is said to suffer from torsional strain, and by a rotation around the carbon carbon bond to the staggered conformation around 12.5 kJ/mol of torsional ...
The textbook explanation for the existence of the energy maximum for an eclipsed conformation in ethane is steric hindrance, but, with a C-C bond length of 154 pm and a Van der Waals radius for hydrogen of 120 pm, the hydrogen atoms in ethane are never in each other's way. The question of whether steric hindrance is responsible for the eclipsed ...
The missing wedge results in a lack of resolution in sample depth, as the missing information is mostly along the z-axis. The missing wedge is also a problem in 3D electron crystallography , where it is usually solved by merging multiple datasets that overlap each other or through symmetry expansion where possible. [ 15 ]
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In a now-viral video on TikTok, bride-to-be Kate O'Neill explains how her fiancé Michael O'Malley developed an "insane but practical" way to cut down their wedding guest list
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