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Pseudo-Voigt approximation. The pseudo-Voigt profile (or pseudo-Voigt function) is an approximation of the Voigt profile V (x) using a linear combination of a Gaussian curve G (x) and a Lorentzian curve L (x) instead of their convolution. The pseudo-Voigt function is often used for calculations of experimental spectral line shapes.
Gaussian function. In mathematics, a Gaussian function, often simply referred to as a Gaussian, is a function of the base form and with parametric extension for arbitrary real constants a, b and non-zero c. It is named after the mathematician Carl Friedrich Gauss. The graph of a Gaussian is a characteristic symmetric "bell curve" shape.
Curve fitting. Fitting of a noisy curve by an asymmetrical peak model, with an iterative process (Gauss–Newton algorithm with variable damping factor α). Curve fitting[1][2] is the process of constructing a curve, or mathematical function, that has the best fit to a series of data points, [3] possibly subject to constraints. [4][5] Curve ...
This allows to calculated the heights of each Gaussian curve in each spectrum (N sol ·N pks parameters) by a (fast) linear least squares fitting procedure, while the and w parameters (2·N pks parameters) can be obtained with a non-linear least-square fitting on the data from all spectra simultaneously, thus reducing dramatically the ...
The exponentially modified normal distribution is another 3-parameter distribution that is a generalization of the normal distribution to skewed cases. The skew normal still has a normal-like tail in the direction of the skew, with a shorter tail in the other direction; that is, its density is asymptotically proportional to for some positive .
Probability distribution fitting. Probability distribution fitting or simply distribution fitting is the fitting of a probability distribution to a series of data concerning the repeated measurement of a variable phenomenon. The aim of distribution fitting is to predict the probability or to forecast the frequency of occurrence of the magnitude ...
Gaussian process is a powerful non-linear interpolation tool. Many popular interpolation tools are actually equivalent to particular Gaussian processes. Gaussian processes can be used not only for fitting an interpolant that passes exactly through the given data points but also for regression; that is, for fitting a curve through noisy data.
Probability theory. In probability theory and statistics, a normal distribution or Gaussian distribution is a type of continuous probability distribution for a real-valued random variable. The general form of its probability density function is The parameter is the mean or expectation of the distribution (and also its median and mode), while ...