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Adams' catalyst, also known as platinum dioxide, is usually represented as platinum(IV) oxide hydrate, PtO 2 •H 2 O. It is a catalyst for hydrogenation and hydrogenolysis in organic synthesis . [ 1 ]
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When heated to 150–180 °C, it decomposes with autooxidation to plutonium (VI) with the formation of plutonyl nitrate (PuO 2 (NO 3) 2).Upon evaporation of concentrated nitric acid solutions of plutonium nitrate and alkali metal nitrates, double nitrates of the composition Me 2 [Pu(NO 3) 6] are formed, where Me = Cs +, Rb +, K +, Tl +, NH 4 +, analogous to ceric ammonium nitrate.
Cerium(IV) nitrate – Ce(NO 3) 4; Cerium(IV) oxide – CeO 2; Cerium(IV) sulfate – Ce(SO 4) 2; Cerium(III,IV) oxide – Ce 3 O 4; Ceric ammonium nitrate – (NH 4) 2 Ce(NO 3) 6; Cerium hexaboride – CeB 6; Cerium aluminium – CeAl; Cerium cadmium – CeCd; Cerium magnesium – CeMg; Cerium mercury – CeHg; Cerium silver – CeAg; Cerium ...
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Other names plutonium mononitride, azanylidyneplutonium, plutonium(III) nitride. Identifiers CAS Number. ... PuCl 3 + 1/ 2 N 2 + 3 / 2 H 2 → PuN + 3HCl (at 800 ...
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