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Distillation, also classical distillation, is the process of separating the component substances of a liquid mixture of two or more chemically discrete substances; the separation process is realized by way of the selective boiling of the mixture and the condensation of the vapors in a still.
A McCabe–Thiele diagram for the distillation of a binary (two-component) feed is constructed using the vapor-liquid equilibrium (VLE) data—which is how vapor is concentrated when in contact with its liquid form—for the component with the lower boiling point. Figure 1: Typical McCabe–Thiele diagram for distillation of a binary feed
The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the ...
For instance, in a distillation of ethanol and water, water will boil out of the remaining ethanol, rather than the ethanol out of the water as at lower concentrations. Overall the pressure-swing distillation is a very robust and not so highly sophisticated method compared to multi component distillation or membrane processes, but the energy ...
In this example, a mixture of 96% ethanol and 4% water boils at 78.2 °C (172.8 °F); the mixture is more volatile than pure ethanol. For this reason, ethanol cannot be completely purified by direct fractional distillation of ethanol–water mixtures. The apparatus is assembled as in the diagram.
Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula CH 3 CH 2 OH. It is an alcohol , with its formula also written as C 2 H 5 OH , C 2 H 6 O or EtOH, where Et stands for ethyl .
Extractive distillation is defined as distillation in the presence of a miscible, high-boiling, relatively non-volatile component, the solvent, that forms no azeotrope with the other components in the mixture. The method is used for mixtures having a low value of relative volatility, nearing unity. Such mixtures cannot be separated by simple ...
For example, if the gas entering the condenser is a mixture of 25% ethanol vapor and 75% carbon dioxide (by moles) at 100 kPa (typical atmospheric pressure), the condensation surface must be kept below 48 °C, the boiling point of ethanol at 25 kPa.