Search results
Results from the WOW.Com Content Network
Calcium peroxide or calcium dioxide is the inorganic compound with the formula CaO 2. It is the peroxide (O 2 2−) salt of Ca 2+. Commercial samples can be yellowish, but the pure compound is white. It is almost insoluble in water. [3]
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero.
This translates into the smaller force constant of the bond (2.8 N/cm vs. 11.4 N/cm for 3 O 2) and the lower frequency of the molecular vibration (770 cm −1 vs. 1555 cm −1 for 3 O 2). [2] The peroxide ion can be compared with superoxide O − 2, which is a radical, and dioxygen, a diradical. [2]
The exact relationship depends on the nature of the reactions at the two electrodes. For the electrolysis of aqueous copper(II) sulfate (CuSO 4) as an example, with Cu 2+ (aq) and SO 2− 4 (aq) ions, the cathode reaction is the reduction Cu 2+ (aq) + 2 e − → Cu(s) and the anode reaction is the corresponding oxidation of Cu to Cu 2+.
Sodium cyanate is isostructural with sodium fulminate, confirming the linear structure of the cyanate ion. [3] It is made industrially by heating a mixture of sodium carbonate and urea. [4] Na 2 CO 3 + 2 OC(NH 2) 2 → 2 NaNCO + CO 2 + 2 NH 3 + H 2 O. A similar reaction is used to make potassium cyanate. Cyanates are produced when cyanides are ...
2OC(NH 2) 2 + Na 2 CO 3 → 2Na(NCO) + CO 2 + 2NH 3 + H 2 O. Sodium allophanate is observed as an intermediate: [2] H 2 NC(O)NHCO 2 Na → NaOCN + NH 3 + CO 2. It can also be prepared in the laboratory by oxidation of a cyanide in aqueous solution by a mild oxidizing agent such as lead oxide. [3]
Sodium periodate is an inorganic salt, composed of a sodium cation and the periodate anion.It may also be regarded as the sodium salt of periodic acid.Like many periodates, it can exist in two different forms: sodium metaperiodate (formula NaIO 4) and sodium orthoperiodate (normally Na 2 H 3 IO 6, but sometimes the fully reacted salt Na 5 IO 6).
The structure of sodium oxide has been determined by X-ray crystallography.Most alkali metal oxides M 2 O (M = Li, Na, K, Rb) crystallise in the antifluorite structure.In this motif the positions of the anions and cations are reversed relative to their positions in CaF 2, with sodium ions tetrahedrally coordinated to 4 oxide ions and oxide cubically coordinated to 8 sodium ions.