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Silicon monoxide is the chemical compound with the formula SiO where silicon is present in the oxidation state +2. In the vapour phase, it is a diatomic molecule. [1] It has been detected in stellar objects [2] and has been described as the most common oxide of silicon in the universe.
A suboxide of caesium is Cs 11 O 3, where the charge on Cs is clearly less than 1+, but the oxide is still described as O 2−. Suboxides typically feature extensive bonding between the electropositive element, often leading to clusters. Examples of suboxides other than alkali metal derivatives: [2] Carbon suboxide, C 3 O 2; Boron suboxide, B 6 O;
A silicon–oxygen bond (Si−O bond) is a chemical bond between silicon and oxygen atoms that can be found in many inorganic and organic compounds. [1] In a silicon–oxygen bond, electrons are shared unequally between the two atoms , with oxygen taking the larger share due to its greater electronegativity .
2 Si + 3 H 2 O → Na 2 SiO 3 + 3 H 2 Mg 2 Si + 2 H 2 SO 4 → 2 MgSO 4 + SiH 4. Products often vary with the stoichiometry of the silicide reactant. For example, Ca 2 Si is polar and non-conducting and has the anti-PbCl 2 structure with single isolated silicon atoms, and reacts with water to produce calcium hydroxide, hydrated silicon dioxide ...
Unconfirmed reports exist for nonequilibrium Si 2 O, Si 3 O 2, Si 3 O 4, Si 2 O 3 and Si 3 O 5. [94] Silicon sulfide is also a chain compound. Cyclic SiS 2 has been reported to exist in the gas phase. [95] The phase diagram of silicon with selenium has two phases: SiSe 2 and SiSe. [96] Tellurium silicide is a semiconductor with formula TeSi 2 ...
Two oxides of germanium are known: germanium dioxide (GeO 2, germania) and germanium monoxide, (GeO). [4] The dioxide, GeO 2 can be obtained by roasting germanium disulfide (GeS 2) or by allowing elemental germanium to slowly oxidze in air, [5] and is a white powder that is only slightly soluble in water but reacts with alkalis to form germanates. [4]
Silylene is a chemical compound with the formula SiR 2.It is the silicon analog of carbene.Due to presence of a vacant p orbital, silylene rapidly reacts in a bimolecular manner [clarification needed] when condensed.
[3] [4] The parameters of the cubic phase are listed in the infobox. The rhombohedral phase is produced at high temperatures and pressures or when using non-equilibrium growth methods. [5] It has a space group R 3 c No. 167, Pearson symbol hR30, a = 0.5487 nm, b = 0.5487 nm, c = 1.4510 nm, Z = 6 and calculated density 7.31 g/cm 3. [6]