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Nitric acid is an inorganic compound with the formula H N O 3.It is a highly corrosive mineral acid. [6] The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into oxides of nitrogen.
Upon mixing of concentrated hydrochloric acid and concentrated nitric acid, chemical reactions occur. These reactions result in the volatile products nitrosyl chloride and chlorine gas: HNO 3 + 3 HCl → NOCl + Cl 2 + 2 H 2 O. as evidenced by the fuming nature and characteristic yellow color of aqua regia.
Mercury(I) nitrate is an inorganic compound, a salt of mercury and nitric acid with the formula Hg 2 (NO 3) 2. A yellow solid, the compound is used as a precursor to other Hg 2 2+ complexes. The structure of the hydrate has been determined by X-ray crystallography. It consists of a [H 2 O-Hg-Hg-OH 2] 2+ center, with a Hg-Hg distance of 254 pm. [2]
Commonly used mineral acids are sulfuric acid (H 2 SO 4), hydrochloric acid (HCl) and nitric acid (HNO 3); these are also known as bench acids. [1] Mineral acids range from superacids (such as perchloric acid) to very weak ones (such as boric acid). Mineral acids tend to be very soluble in water and insoluble in organic solvents.
Nitrous acid (molecular formula H N O 2) is a weak and monoprotic acid known only in solution, in the gas phase, and in the form of nitrite (NO − 2) salts. [3] It was discovered by Carl Wilhelm Scheele, who called it "phlogisticated acid of niter". Nitrous acid is used to make diazonium salts from amines.
The pentahydrate is the most common form. It is crystallized from dilute nitric acid solution. [4] The tetrahydrate, Th(NO 3) 4 •4H 2 O is formed by crystallizing from a stronger nitric acid solution. Concentrations of nitric acid from 4 to 59% result in the tetrahydrate forming. [2]
Mixture of nitric and acetic acids or nitric acid and acetic anhydride is commercially important in the production of RDX, as amines are destructed by sulfuric acid. Acetyl nitrate had also been used as a nitration agent. [14] [15] In the Wolffenstein–Böters reaction, benzene reacts with nitric acid and mercury(II) nitrate to give picric acid.
Mixtures of ordinary nitric acid in sulfuric acid therefore contain substantial amounts of water and are unsuitable for processes such as those that occur in the manufacture of trinitrotoluene. The synthesis of RDX and certain other explosives does not require oleum. [10] Anhydrous nitric acid, referred to as white fuming nitric acid, can be ...