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Benzyl is most commonly abbreviated Bn. For example, benzyl alcohol can be represented as BnOH. Less common abbreviations are Bzl and Bz, the latter of which is ambiguous as it is also the standard abbreviation for the benzoyl group C 6 H 5 C(O)−. Likewise, benzyl should not be confused with the phenyl group C 6 H 5 −, abbreviated Ph.
The ether linkage is highly stable, but the methyl group can be removed with strong acids, such as hydroiodic acid or boron trichloride: [5]: 565–566 CH 3 OC 6 H 5 + HI → HOC 6 H 5 + CH 3 I. Birch reduction of anisole gives 1-methoxycyclohexa-1,4-diene. [6]
In chemistry, a phenol ether (or aromatic ether) is an organic compound derived from phenol (C 6 H 5 OH), where the hydroxyl (-OH) group is substituted with an alkoxy (-OR) group. Usually phenol ethers are synthesized through the condensation of phenol and an organic alcohol ; however, other known reactions regarding the synthesis of ethers can ...
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An ethoxy group (CH 3 CH 2 O−) is found in the organic compound ethyl phenyl ether (C 6 H 5 OCH 2 CH 3, also known as ethoxybenzene). Related to alkoxy groups are aryloxy groups, which have an aryl group singularly bonded to oxygen such as the phenoxy group (C 6 H 5 O−). An alkoxy or aryloxy group bonded to an alkyl or aryl (R−O−R') is ...
Ether cleavage refers to chemical substitution reactions that lead to the cleavage of ethers. Due to the high chemical stability of ethers, the cleavage of the C-O bond is uncommon in the absence of specialized reagents or under extreme conditions. [1] [2] In organic chemistry, ether cleavage is an acid catalyzed nucleophilic substitution reaction.
o-Cresol is mainly used as a precursor to other compounds.Chlorination and etherification gives members of commercially important herbicides, such as 2-methyl-4-chlorophenoxyacetic acid (MCPA).
A 1,2-Wittig rearrangement is a categorization of chemical reactions in organic chemistry, and consists of a 1,2-rearrangement of an ether with an alkyllithium compound. [1] The reaction is named for Nobel Prize winning chemist Georg Wittig. [2] [3] The intermediate is an alkoxy lithium salt, and the final product an alcohol.