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A review by Berthod [19] studied the combined theories presented above and applied the Knox equation to independently determine the cause of the reduced efficiency. The Knox equation is commonly used in HPLC to describe the different contributions to overall band broadening of a solute. The Knox equation is expressed as: h = An^(1/3)+ B/n + Cn ...
The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
HPLC has many applications in both laboratory and clinical science. It is a common technique used in pharmaceutical development, as it is a dependable way to obtain and ensure product purity. [59] While HPLC can produce extremely high quality (pure) products, it is not always the primary method used in the production of bulk drug materials. [60]
The resulting system of linear algebraic equations Linear equation can then be solved to obtain at the nodal points. The matrix of higher order can be solved in MATLAB. This method can also be applied to a 2D situation. See Finite volume method for two dimensional diffusion problem.
The Cambridge Handbook of Physics Formulas. Cambridge University Press. ISBN 978-0-521-57507-2. A. Halpern (1988). 3000 Solved Problems in Physics, Schaum Series. Mc Graw Hill. ISBN 978-0-07-025734-4. R.G. Lerner, G.L. Trigg (2005). Encyclopaedia of Physics (2nd ed.). VHC Publishers, Hans Warlimont, Springer. pp. 12– 13.
Equation [3] involves the average velocity v + v 0 / 2 . Intuitively, the velocity increases linearly, so the average velocity multiplied by time is the distance traveled while increasing the velocity from v 0 to v, as can be illustrated graphically by plotting velocity against time as a straight line graph. Algebraically, it follows ...
The linear motion can be of two types: uniform linear motion, with constant velocity (zero acceleration); and non-uniform linear motion, with variable velocity (non-zero acceleration). The motion of a particle (a point-like object) along a line can be described by its position x {\displaystyle x} , which varies with t {\displaystyle t} (time).
A twist is a screw used to represent the velocity of a rigid body as an angular velocity around an axis and a linear velocity along this axis. All points in the body have the same component of the velocity along the axis, however the greater the distance from the axis the greater the velocity in the plane perpendicular to this axis.