Search results
Results from the WOW.Com Content Network
Malononitrile is an organic compound nitrile with the formula CH 2 (CN) 2. It is a colorless or white solid, although aged samples appear yellow or even brown. It is a colorless or white solid, although aged samples appear yellow or even brown.
Like most azobenzenes, Solvent Yellow 7 can be synthesized by the reaction of the phenyldiazonium salt with phenol.The optimal pH value for this azo coupling is 8.5-10. The reaction is carried out in water, since sodium chloride (or potassium chloride) formed in the reaction is soluble in water, while the product precipitates.
Photochemical rearrangement of DAMN under UV light gives 4-aminoimidazole-5-carbonitrile (AICN), which can react further to form various nucleobases. [8] [9] Early experiments have also suggested that certain amino acids, such as aspartic acid, alanine, and glycine, may have their probiotic origins in the acidic hydrolysis of diaminomaleonitrile.
Nucleophilic attack at the ester group, as part of acyl substitution: reaction with ammonia leads to cyanoacetamide, which can be converted by dehydration with PCl 5 or POCl 3 to malononitrile. [11] Via the acidic methylene group as a nucleophile; Ethyl cyanoacetate is a building block for the synthesis of heterocycles which are used for ...
Sodium maleonitriledithiolate is the chemical compound described by the formula Na 2 S 2 C 2 (CN) 2. The name refers to the cis compound, structurally related to maleonitrile ((CH(CN)) 2). Maleonitriledithiolate is often abbreviated mnt. It is a "dithiolene", i.e. a chelating alkene-1,2-dithiolate.
It reacts with malononitrile to form 2-imino-6-methoxy-2H-1-benzopyran-3-carbonitrile. [2] It can be reduced by sodium borohydride in ethanol to form 2-hydroxy-5-methoxybenzyl alcohol. [ 3 ]
The compound 2-chlorobenzalmalononitrile (also called o-chlorobenzylidene malononitrile; chemical formula: C 10 H 5 ClN 2), a cyanocarbon, is the defining component of the lachrymatory agent commonly referred to as CS gas, a tear gas which is used as a riot control agent, and is banned for use in warfare due to the 1925 Geneva Protocol.
Tetramethylsuccinonitrile or TMSN is an organic compound with the formula (C(CH 3) 2 CN) 2, classified as a dinitrile, and a colorless and odorless solid derived from 2,2'-azobis-isobutyronitrile, a common radical initiator in the manufacture of PVC: [(CH 3) 2 C(CN)] 2 N 2 → [(CH 3) 2 C(CN)] 2 + N 2. [6]