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During engine shutdown, fuel flow goes to zero rapidly, while the engine is still quite hot. Residual and trapped fuel can polymerize or even carbonize at hot spots or in hot components. Even without hot spots, heavy fuels can create a petroleum residue, as can be seen in gasoline, diesel, or jet fuel tanks that have been in service for years.
The heat of combustion of kerosene is similar to that of diesel fuel; its lower heating value is 43.1 MJ/kg (around 18,500 Btu/lb), and its higher heating value is 46.2 MJ/kg (19,900 Btu/lb). [15] ASTM International recognizes two grades of kerosene: 1-K (less than 0.04% sulfur by weight) and 2-K (0.3% sulfur by weight). [16]
Jet fuel is more expensive than diesel fuel but the logistical advantages of using one fuel can offset the extra expense of its use in certain circumstances. Jet fuel contains more sulfur, up to 1,000 ppm, which therefore means it has better lubricity and does not currently require a lubricity additive as all pipeline diesel fuels require.
Conventional diesel is similar to gasoline in that it is a mixture of aliphatic hydrocarbons extracted from petroleum. Diesel may cost more or less than gasoline, but generally costs less to produce because the extraction processes used are simpler. Some countries (particularly Canada, India and Italy) also have lower tax rates on diesel fuels.
Liquid hydrocarbons (fuels such as gasoline, diesel and kerosene) are today the densest way known to economically store and transport chemical energy at a large scale (1 kg of diesel fuel burns with the oxygen contained in ≈ 15 kg of air). Burning local biomass fuels supplies household energy needs (cooking fires, oil lamps, etc.) worldwide.
In all, the higher heating value of hydrogen is 18.2% above its lower heating value (142 MJ/kg vs. 120 MJ/kg). For hydrocarbons, the difference depends on the hydrogen content of the fuel. For gasoline and diesel the higher heating value exceeds the lower heating value by about 10% and 7%, respectively, and for natural gas about 11%.
North American distillate is broadly described as a fuel with heavier molecular weight than gasoline, and similar to or lighter than kerosene or No. 1 fuel oil. However, both usage of the term and formulation of the product varied widely. Octane ratings varied similarly, between 33 and 45. [1] [2]
Kerosene-based fuel has a much higher flash point than gasoline-based fuel, meaning that it requires significantly higher temperature to ignite. It is a high-quality fuel; if it fails the purity and other quality tests for use on jet aircraft, it is sold to ground-based users with less demanding requirements, such as railroads.
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