Search results
Results from the WOW.Com Content Network
Main page; Contents; Current events; Random article; About Wikipedia; Contact us
6) are structurally equivalent to each other, as are the two carbons; because any hydrogen can be switched with any other, either by a permutation that swaps just those two atoms, or by a permutation that swaps the two carbons and each hydrogen in one methyl group with a different hydrogen on the other methyl. Either operation preserves the ...
A methylene group is any part of a molecule that consists of two hydrogen atoms bound to a carbon atom, which is connected to the remainder of the molecule by two single bonds. [1] The group may be represented as −CH 2 − or >CH 2 , where the '>' denotes the two bonds.
In chemistry an eclipsed conformation is a conformation in which two substituents X and Y on adjacent atoms A, B are in closest proximity, implying that the torsion angle X–A–B–Y is 0°. [1] Such a conformation can exist in any open chain, single chemical bond connecting two sp 3-hybridised atoms, and it is normally a conformational ...
Bicycloalkanes are alkanes containing two rings that are connected to each other by sharing two carbon atoms. Orientation within bicycloalkanes is dependent on the cis or trans orientation of the hydrogen shared by the different rings instead of the methyl groups present in the rings. [7] Tetrodotoxin is one of the world's most potent toxins ...
Two methyl groups are the substituents attached to the central oxygen in diethyl ether. Because the two methyl groups are electropositive, greater s character will be observed and the real bond angle is larger than the ideal bond angle of 109.5 o. Methanol has one electropositive methyl substituent and one electronegative hydrogen substituent.
It occurs only when two hydrogen atoms on a methylene group differ stereochemically from each other. The geminal coupling constant is referred to as 2 J since the hydrogen atoms couple through two bonds. Depending on the other substituents, the geminal coupling constant takes values between −23 and +42 Hz. [3] [4]
Ipso-substitution describes two substituents sharing the same ring position in an intermediate compound in an electrophilic aromatic substitution. Trimethylsilyl, tert-butyl, and isopropyl groups can form stable carbocations, hence are ipso directing groups. Meso-substitution refers to the substituents occupying a benzylic position.