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Liquefaction of gases is physical conversion of a gas into a liquid state (condensation). The liquefaction of gases is a complicated process that uses various compressions and expansions to achieve high pressures and very low temperatures, using, for example, turboexpanders .
As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to allow separation of the constituents, such as oxygen, nitrogen, and the noble gases." [4] Another is the conversion of solid coal into a liquid form usable as a substitute for liquid fuels. [5]
Liquefied natural gas is natural gas that has been liquefied for the purpose of storage or transport. Since transportation of natural gas requires a large network of pipeline that crosses through various terrains and oceans, a huge investment and long term planning are required.
An example of this is during the 1989 earthquake in San Francisco when sand boils brought up debris from the 1906 earthquake. This process is a result of liquefaction. By mapping the location of sand boils that erupted in the Marina District during the 1989 Loma Prieta earthquake, scientists discovered the site of a lagoon that existed in 1906.
The high pressure gas is then cooled by immersing the gas in a cooler environment; the gas loses some of its energy (heat). Linde's patent example gives an example of brine at 10°C. The high pressure gas is further cooled with a countercurrent heat exchanger; the cooler gas leaving the last stage cools the gas going to the last stage.
The heating value depends on the source of gas that is used and the process that is used to liquefy the gas. The range of heating value can span ±10 to 15 percent. A typical value of the higher heating value of LNG is approximately 50 MJ/kg or 21,500 BTU/lb. [2] A typical value of the lower heating value of LNG is 45 MJ/kg or 19,350 BTU/lb.
Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals.This process is often known as "coal to X" or "carbon to X", where X can be many different hydrocarbon-based products.
Hydrothermal liquefaction (HTL) is a thermal depolymerization process used to convert wet biomass, and other macromolecules, into crude-like oil under moderate temperature and high pressure. [1] The crude-like oil has high energy density with a lower heating value of 33.8-36.9 MJ/kg and 5-20 wt% oxygen and renewable chemicals.