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Manganese carbonate decomposes with release of carbon dioxide, i.e. calcining, at 200 °C to give MnO 1.88: MnCO 3 + 0.44 O 2 → MnO 1.8 + CO 2. This method is sometimes employed in the production of manganese dioxide, which is used in dry-cell batteries and for ferrites. [3] Manganese carbonate is widely used as an additive within plant ...
Rhodochrosite forms a complete solid solution series with iron carbonate . Calcium (as well as magnesium and zinc, to a limited extent) frequently substitutes for manganese in the structure, leading to lighter shades of red and pink, depending on the degree of substitution. This is the reason for the rose color of rhodochrosite.
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Manganese may also form mixed oxides with other metals : Bixbyite, (Fe III,Mn III) 2 O 3, a manganese(III) iron(III) oxide mineral; Jacobsite, Mn II Fe III 2 O 4, a manganese(II) iron(III) oxide mineral; Columbite, (Fe II,Mn II)Nb 2 O 6, a niobate of iron(II) and manganese(II) Tantalite, (Fe II,Mn II)Ta 2 O 6, a tantalum(V) mineral group close ...
Manganocalcite. Manganoan calcite or manganocalcite is a variety of calcite rich in manganese, which gives the mineral a pink color. [1] Its chemical formula is (Ca,Mn)CO 3.It was first reported from the Banská Štiavnica Mining District, Slovak Republic, [1] but is widely distributed around the world, notably in the Cave of Swords at Naica, Chihuahua, Mexico as well as in Bulgaria.
The anhydrous form is predicted to be isostructural with cobalt(II) perchlorate, based on the IR spectrum and the Raman spectrum of the compound. [3] The hexahydrate consists of discrete [Mn(H 2 O) 6] 2+ octahedrons and perchlorate anions with lattice constants a = 7.85 Å, b = 13.60 Å and c = 5.30 Å. The hexahydrate undergoes phase ...
Manganese(II) nitrate is the precursor to manganese(II) carbonate (MnCO 3), which is used in fertilizers and as a colourant. The advantage of this method, based on the use of ammonia ( NH 3 ) and carbon dioxide (CO 2 ) as reaction intermediates, being that the side product ammonium nitrate ( NH 4 NO 3 ) is also useful as a fertilizer.
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