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Vapor pressure [a] or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate.
Atmospheric thermodynamics is the study of heat-to-work transformations (and their reverse) that take place in the Earth's atmosphere and manifest as weather or climate. . Atmospheric thermodynamics use the laws of classical thermodynamics, to describe and explain such phenomena as the properties of moist air, the formation of clouds, atmospheric convection, boundary layer meteorology, and ...
Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
The equilibrium concentration of each component in the liquid phase is often different from its concentration (or vapor pressure) in the vapor phase, but there is a relationship. The VLE concentration data can be determined experimentally or approximated with the help of theories such as Raoult's law, Dalton's law, and Henry's law.
The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
Vaporization (or vapo(u)risation) of an element or compound is a phase transition from the liquid phase to vapor. [1] There are two types of vaporization: evaporation and boiling . Evaporation is a surface phenomenon , whereas boiling is a bulk phenomenon (a phenomenon in which the whole object or substance is involved in the process).
The vapour pressure above the curved interface is then higher than that for the planar interface. This picture provides a simple conceptual basis for the Kelvin equation. The change in vapor pressure can be attributed to changes in the Laplace pressure. When the Laplace pressure rises in a droplet, the droplet tends to evaporate more easily.
The simplest definition is that an ideal solution is a solution for which each component obeys Raoult's law = for all compositions. Here p i {\displaystyle p_{i}} is the vapor pressure of component i {\displaystyle i} above the solution, x i {\displaystyle x_{i}} is its mole fraction and p i ∗ {\displaystyle p_{i}^{*}} is the vapor pressure ...