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A network solid or covalent network solid (also called atomic crystalline solids or giant covalent structures) [1] [2] is a chemical compound (or element) in which the atoms are bonded by covalent bonds in a continuous network extending throughout the material.
Solids can be classified according to the nature of the bonding between their atomic or molecular components. The traditional classification distinguishes four kinds of bonding: [1] Covalent bonding, which forms network covalent solids (sometimes called simply "covalent solids") Ionic bonding, which forms ionic solids
In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
Molecular solids have low melting (T m) and boiling (T b) points compared to metal (iron), ionic (sodium chloride), and covalent solids (diamond). [ 4 ] [ 5 ] [ 8 ] [ 13 ] Examples of molecular solids with low melting and boiling temperatures include argon , water , naphthalene , nicotine , and caffeine (see table below).
This page was last edited on 20 July 2010, at 03:13 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may ...
In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central ion/molecule/atom is called a ligand .
The synthesis of such entangled architectures has been made efficient by combining supramolecular chemistry with traditional covalent synthesis, however mechanically interlocked molecular architectures have properties that differ from both "supramolecular assemblies" and "covalently bonded molecules". The terminology "mechanical bond" has been ...
While at University of Michigan, Omar M. Yaghi (currently at UCBerkeley) and Adrien P Cote published the first paper of COFs in 2005, reporting a series of 2D COFs. [5] They reported the design and successful synthesis of COFs by condensation reactions of phenyl diboronic acid (C 6 H 4 [B(OH) 2] 2) and hexahydroxytriphenylene (C 18 H 6 (OH) 6).