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Electron ionization mass spectrum of toluene. Note parent peak corresponding to molecular mass M = 92 (C 7 H 8 +) and highest peak at M-1 = 91 (C 7 H 7 +, quasi-stable tropylium cation). A mass spectrum is a histogram plot of intensity vs. mass-to-charge ratio (m/z) in a chemical sample, [1] usually acquired using an instrument called a mass ...
The compound is an alkylating agent, [2] and as such is handled cautiously. Chloroacetonitrile is also generated in situ by the reaction of acetonitrile with sulfur monochloride . A second chlorination gives dichloro acetonitrile , which undergoes cycloaddition with sulfur monochloride to give 4,5-dichloro-1,2,3-dithiazolium chloride : [ 3 ]
Ion mobility spectrometry-mass spectrometry (IMS/MS or IMMS) is a technique where ions are first separated by drift time through some neutral gas under an applied electrical potential gradient before being introduced into a mass spectrometer. [43] Drift time is a measure of the collisional cross section relative to the charge of the ion.
The mass spectrum of methylbromide has two prominent peaks of equal intensity at m/z 94 (M) and 96 (M+2) and then two more at 79 and 81 belonging to the bromine fragment. Even when compounds only contain elements with less intense isotope peaks ( carbon or oxygen ), the distribution of these peaks can be used to assign the spectrum to the ...
A mass chromatogram is a representation of mass spectrometry data as a chromatogram, where the x-axis represents time and the y-axis represents signal intensity. [1] The source data contains mass information; however, it is not graphically represented in a mass chromatogram in favor of visualizing signal intensity versus time.
In mass spectrometry, direct analysis in real time (DART) is an ion source that produces electronically or vibronically excited-state species from gases such as helium, argon, or nitrogen that ionize atmospheric molecules or dopant molecules. The ions generated from atmospheric or dopant molecules undergo ion-molecule reactions with the sample ...
Trapped fragment ions or their ion-molecule reaction products can be re-excited for multistage mass spectrometry (MS n). [5] If the excitation is not applied on the resonant frequency, but at a slightly off-resonant frequency, the ions will alternately be excited and de-excited, permitting multiple collisions at low collision energy.
Chlorine (17 Cl) has 25 isotopes, ranging from 28 Cl to 52 Cl, and two isomers, 34m Cl and 38m Cl. There are two stable isotopes, 35 Cl (75.8%) and 37 Cl (24.2%), giving chlorine a standard atomic weight of 35.45.