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  2. Work-up - Wikipedia

    en.wikipedia.org/wiki/Work-up

    separating the reaction mixture into organic and aqueous layers by liquid-liquid extraction. removal of solvents by evaporation. purification by chromatography, distillation or recrystallization. The work-up steps required for a given chemical reaction may require one or more of these manipulations.

  3. Alpha hydroxycarboxylic acid - Wikipedia

    en.wikipedia.org/wiki/Alpha_hydroxycarboxylic_acid

    They have the general chemical formula, HO 2 C(CHOH) n CH 2 OH. Gluconic acid , a particularly common aldonic acid, the oxidized derivative of glucose . 2-Hydroxy-4-(methylthio)butyric acid is an intermediate in the biosynthesis of 3-dimethylsulfoniopropionate , precursor to natural dimethyl sulfide .

  4. McMurry reaction - Wikipedia

    en.wikipedia.org/wiki/McMurry_reaction

    The McMurry reaction of benzophenone. The McMurry reaction is an organic reaction in which two ketone or aldehyde groups are coupled to form an alkene using a titanium chloride compound such as titanium(III) chloride and a reducing agent.

  5. Reaction mechanism - Wikipedia

    en.wikipedia.org/wiki/Reaction_mechanism

    In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. [1] A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases.

  6. Metal aquo complex - Wikipedia

    en.wikipedia.org/wiki/Metal_aquo_complex

    Chromium(II) ion in aqueous solution. Most aquo complexes are mono-nuclear, with the general formula [M(H 2 O) 6] n+, with n = 2 or 3; they have an octahedral structure. The water molecules function as Lewis bases, donating a pair of electrons to the metal ion and forming a dative covalent bond with it. Typical examples are listed in the ...

  7. Nicotinamide adenine dinucleotide - Wikipedia

    en.wikipedia.org/wiki/Nicotinamide_adenine_di...

    Such reactions (summarized in formula below) involve the removal of two hydrogen atoms from the reactant (R), in the form of a hydride ion (H −), and a proton (H +). The proton is released into solution, while the reductant RH 2 is oxidized and NAD + reduced to NADH by transfer of the hydride to the nicotinamide ring. RH 2 + NAD + → NADH ...

  8. Aqueous two-phase system - Wikipedia

    en.wikipedia.org/wiki/Aqueous_two-phase_system

    It is a common observation that when oil and water are poured into the same container, they separate into two phases or layers, because they are immiscible.In general, aqueous (or water-based) solutions, being polar, are immiscible with non-polar organic solvents (cooking oil, chloroform, toluene, hexane etc.) and form a two-phase system.

  9. Rate-determining step - Wikipedia

    en.wikipedia.org/wiki/Rate-determining_step

    Another example is the unimolecular nucleophilic substitution (S N 1) reaction in organic chemistry, where it is the first, rate-determining step that is unimolecular. A specific case is the basic hydrolysis of tert-butyl bromide (t-C 4 H 9 Br) by aqueous sodium hydroxide. The mechanism has two steps (where R denotes the tert-butyl radical t-C ...