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For example, potassium permanganate dissolves in benzene in the presence of 18-crown-6, giving the so-called "purple benzene", which can be used to oxidize diverse organic compounds. [1] Various substitution reactions are also accelerated in the presence of 18-crown-6, which suppresses ion-pairing. [10] The anions thereby become naked nucleophiles.
Benzonitrile is a useful solvent and a versatile precursor to many derivatives. It reacts with amines to afford N-substituted benzamides after hydrolysis. [3] It is a precursor to diphenylmethanimine via reaction with phenylmagnesium bromide followed by methanolysis.
Solubility tables; Substance Formula 0 °C 10 °C 15 °C 20 °C 30 °C 40 °C 50 °C 60 °C 70 °C 80 °C 90 °C 100 °C Actinium(III) hydroxide
The following compounds are liquid at room temperature and are completely miscible with water; ... 1,5-Pentanediol: 111-29-5 (CH 3) 2 CHOH: 2-Propanol: 67-63-0 CH 3 ...
One family of Cr(VI) reagents employs the complex CrO 3 (pyridine) 2. [3] Sarett's reagent: a solution of CrO 3 (pyridine) 2 in pyridine. It was popularized for selective oxidation of primary and secondary alcohols to carbonyl compounds. Collins reagent is a solution of the same CrO 3 (pyridine) 2 but in dichloromethane. The Ratcliffe variant ...
Its structure consists of a benzene ring substituted with a tert-butyl group. It is a flammable colorless liquid which is nearly insoluble in water but miscible with organic solvents. It is a flammable colorless liquid which is nearly insoluble in water but miscible with organic solvents.
The benzilic acid rearrangement is formally the 1,2-rearrangement of 1,2-diketones to form α-hydroxy–carboxylic acids using a base. This reaction receives its name from the reaction of benzil with potassium hydroxide to form benzilic acid. First performed by Justus von Liebig in 1838, [1] it is the first reported example of a rearrangement ...
After exposure to 63 to 405 mg/m 3 of benzene for 1 to 5 hours, 51 to 87% was excreted in the urine as phenol over a period of 23 to 50 hours. In another human study, 30% of absorbed dermally applied benzene, which is primarily metabolized in the liver, was excreted as phenol in the urine.