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The kraft process (also known as kraft pulping or sulfate process) is a process for conversion of wood into wood pulp, which consists of almost pure cellulose fibres, the main component of paper. The kraft process involves treatment of wood chips with a hot mixture of water, sodium hydroxide (NaOH), and sodium sulfide (Na 2 S), known as white ...
The pulp made by this process is known as "stone groundwood" pulp (SGW). If the wood is ground in a pressurized, sealed grinder the pulp is classified as "pressure groundwood" (PGW) pulp. Most modern mills use chips rather than logs and ridged metal discs called refiner plates instead of grindstones.
The pulp produced up to this point in the process can be bleached to produce a white paper product. The chemicals used to bleach pulp have been a source of environmental concern, and recently the pulp industry has been using alternatives to chlorine, such as chlorine dioxide, oxygen, ozone and hydrogen peroxide.
Mechanical pulping is the process in which wood is separated or defibrated mechanically into pulp for the paper industry.. The mechanical pulping processes use wood in the form of logs or chips that are mechanically processes, by grinding stones (from logs) or in refiners (from chips), to separate the fibers.
In 1844, Canadian Charles Fenerty and German Friedrich Gottlob Keller had invented the machine and associated process to make use of wood pulp in papermaking. [15] This innovation ended the nearly 2,000-year use of pulped rags and start a new era for the production of newsprint and eventually almost all paper was made out of pulped wood.
A precursor to the soda pulping process was the paper making process developed by Matthias Koops in 1801 which involved washing wood shavings in limewater, adding soda crystals and then boiling the mixture. [2] Soda pulping was one of the first chemical pulping methods and was invented in 1851 by Burgess (United States) and Watts (England).
The sulfite process is acidic and one of the drawbacks is that the acidic conditions hydrolyze some of the cellulose, which means that sulfite pulp fibers are not as strong as kraft pulp fibers. The yield of pulp (based on wood used) is higher than for kraft pulping and sulfite pulp is easier to bleach .
Early kraft pulp mills discharged black liquor to watercourses. Black liquor is quite toxic to aquatic life, and causes a very dark caramel color in the water. The invention of the recovery boiler by G.H. Tomlinson in the early 1930s was a milestone in the advancement of the kraft process. [7]