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A silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula [SiO(4-2x)−. 4−x] n, where 0 ≤ x < 2. The family includes orthosilicate SiO4− 4 (x = 0), metasilicate SiO2− 3 (x = 1), and pyrosilicate Si2O6− 7 (x = 0.5, n = 2). The name is also used for any salt of such ...
A silicon–oxygen bond (Si−O bond) is a chemical bond between silicon and oxygen atoms that can be found in many inorganic and organic compounds. [1] In a silicon–oxygen bond, electrons are shared unequally between the two atoms, with oxygen taking the larger share due to its greater electronegativity. This polarisation means Si–O bonds ...
Silicon compounds are compounds containing the element silicon (Si). As a carbon group element, silicon often forms compounds in the +4 oxidation state, though many unusual compounds have been discovered that differ from expectations based on its valence electrons, including the silicides and some silanes. Metal silicides, silicon halides, and ...
A silicate mineral is generally an inorganic compound consisting of subunits with the formula [SiO 2+n] 2n−. Although depicted as such, the description of silicates as anions is a simplification. Balancing the charges of the silicate anions are metal cations, M x+. Typical cations are Mg 2+, Fe 2+, and Na +.
The orthosilicate ion or group has tetrahedral shape, with one silicon atom surrounded by four oxygen atoms. In the anion, each oxygen carries a unit negative charge. [4] The Si–O bond is 162 pm long. [5] In organic compounds like tetramethyl orthosilicate, each oxygen is formally neutral and is connected to the rest of the molecule by a ...
In dimeric silicon dioxide there are two oxygen atoms bridging between the silicon atoms with an Si–O–Si angle of 94° and bond length of 164.6 pm and the terminal Si–O bond length is 150.2 pm. The Si–O bond length is 148.3 pm, which compares with the length of 161 pm in α-quartz. The bond energy is estimated at 621.7 kJ/mol. [21]
Oxonitridosilicate. The oxonitridosilicates, also called sions (Si + O + N) or silicon-oxynitrides are inorganic ceramic compounds in which oxygen and nitrogen atoms are bound to a silicon atom. [1] A common variant also has aluminium replacing some silicon. They can be considered as silicates in which nitrogen partially replaces oxygen, or as ...
7 anions are arranged in layers parallel to the (100) plane, with the sodium cations distributed in 24 distinct crystallographic positions, coordinated by 4 to 6 near oxygen atoms. Some of the 4-coordinated sodium atoms can be interpreted as parallel columns of edge-sharing NaO 4 tetrahedra. The columnar arrangement forms tunnels that house the ...