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[12] [13] Copper(II) chloride reacts with several metals to produce copper metal or copper(I) chloride (CuCl) with oxidation of the other metal. To convert copper(II) chloride to copper(I) chloride, it can be convenient to reduce an aqueous solution with sulfur dioxide as the reductant: [8] 2 CuCl 2 + SO 2 + 2 H 2 O → 2 CuCl + 2 HCl + H 2 SO 4
Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl 3. It forms a hexahydrate with the formula [Al(H 2 O) 6 ]Cl 3 , containing six water molecules of hydration .
IR absorption spectrum of copper(I) chloride. Copper(I) chloride, commonly called cuprous chloride, is the lower chloride of copper, with the formula CuCl. The substance is a white solid sparingly soluble in water, but very soluble in concentrated hydrochloric acid. Impure samples appear green due to the presence of copper(II) chloride (CuCl 2).
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+.The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table.
The process was based on the oxidation of hydrogen chloride: 4 HCl + O 2 → 2 Cl 2 + 2H 2 O. The reaction takes place at about 400 to 450 °C in the presence of a variety of catalysts, including copper chloride (CuCl 2). Three companies developed commercial processes for producing chlorine based on the Deacon reaction: [1]
Simplified diagram of the Copper–Chlorine cycle. The copper–chlorine cycle (Cu–Cl cycle) is a four-step thermochemical cycle for the production of hydrogen. The Cu–Cl cycle is a hybrid process that employs both thermochemical and electrolysis steps. It has a maximum temperature requirement of about 530 degrees Celsius.
A solution of zinc chloride in hydrochloric acid is a common flux for stainless steels; it has however to be thoroughly removed afterwards as it would cause pitting corrosion. Another highly effective flux is phosphoric acid; its tendency to polymerize at higher temperatures however limits its applications.
Aluminium–copper alloys (AlCu) are aluminium alloys that consist largely of aluminium (Al) and traces of copper (Cu) as the main alloying elements. Important grades also contain additives of magnesium , iron , nickel and silicon ( AlCu(Mg, Fe, Ni, Si) ), often manganese is also included to increase strength (see aluminium-manganese alloys ).