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The 18-electron rule is a chemical rule of thumb used primarily for predicting and rationalizing formulas for stable transition metal complexes, especially organometallic compounds. [1] The rule is based on the fact that the valence orbitals in the electron configuration of transition metals consist of five ( n −1)d orbitals, one n s orbital ...
In organometallic chemistry, organolithium reagents are chemical compounds that contain carbon–lithium (C–Li) bonds.These reagents are important in organic synthesis, and are frequently used to transfer the organic group or the lithium atom to the substrates in synthetic steps, through nucleophilic addition or simple deprotonation. [1]
Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and selenium, as well.
Structure of [Cp*Al] 4, a main group organometallic compound. Main group organometallic chemistry concerns the preparation and properties of main-group elements directly bonded to carbon. The inventory is large. The compounds exhibit a wide range of properties, including ones that are water-stable and others that are pyrophoric. [1]
In organometallic chemistry, a sandwich compound is a chemical compound featuring a metal bound by haptic, covalent bonds to two arene (ring) ligands. The arenes have the formula C n H n , substituted derivatives (for example C n (CH 3 ) n ) and heterocyclic derivatives (for example BC n H n +1 ).
Transmetalation (alt. spelling: transmetallation) is a type of organometallic reaction that involves the transfer of ligands from one metal to another. It has the general form: M 1 –R + M 2 –R′ → M 1 –R′ + M 2 –R. where R and R′ can be, but are not limited to, an alkyl, aryl, alkynyl, allyl, halogen, or pseudohalogen group.
Insertion reactions are observed in organic, inorganic, and organometallic chemistry. In cases where a metal- ligand bond in a coordination complex is involved, these reactions are typically organometallic in nature and involve a bond between a transition metal and a carbon or hydrogen . [ 1 ]
Group 2 organometallic chemistry refers to the organic derivativess of any group 2 element. It is a subtheme to main group organometallic chemistry . [ 2 ] [ 3 ] By far the most common group 2 organometallic compounds are the magnesium-containing Grignard reagents which are widely used in organic chemistry .