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Robert Wilhelm Eberhard Bunsen (German:; 30 March 1811 [a] – 16 August 1899) was a German chemist. He investigated emission spectra of heated elements, and discovered caesium (in 1860) and rubidium (in 1861) with the physicist Gustav Kirchhoff. [11] The Bunsen–Kirchhoff Award for spectroscopy is named after Bunsen and Kirchhoff.
This laid way for spectrochemical analysis in laboratory and astrophysical science. Bunsen and Kirchhoff applied the optical techniques of Fraunhofer, Bunsen's improved flame source and a highly systematic experimental procedure to a detailed examination of the spectra of chemical compounds. They established the linkage between chemical ...
Gustav Robert Kirchhoff (German: [ˈgʊs.taf ˈkɪʁçhɔf]; 12 March 1824 – 17 October 1887) was a German physicist, chemist and mathematican who contributed to the fundamental understanding of electrical circuits, spectroscopy and the emission of black-body radiation by heated objects.
In 1860, the unexpected appearance of sky-blue and dark red was observed in spectral emissions by Robert Bunsen and Gustav Kirchhoff, leading to the discovery of two alkali metals, caesium and rubidium (dark red). [4] [1] Today, this low-cost method is used in secondary education to teach students to detect metals in samples qualitatively. [2]
Bunsen and Kirchhoff were the first to suggest finding new elements by spectrum analysis. They discovered caesium by its two blue emission lines in a sample of Dürkheim mineral water. [130] The pure metal was eventually isolated in 1882 by Setterberg. [131] 37 Rubidium: 1861 R. Bunsen and G. R. Kirchhoff: 1863 R. Bunsen Bunsen and Kirchhoff ...
Robert Bunsen and Gustav Kirchhoff were the first to establish atomic emission spectroscopy as a tool in chemistry. [1] When an element is burned in a flame, its atoms move from the ground electronic state to the excited electronic state. As atoms in the excited state move back down into the ground state, they emit light.
1860–61: Discovery of caesium and rubidium by Robert Bunsen and Gustav Kirchhoff [139] 1860: Erlenmeyer flask by Emil Erlenmeyer [ 140 ] 1863–64: Discovery of indium by Ferdinand Reich and Hieronymous Theodor Richter [ 141 ] [ 142 ] [ 143 ]
About 45 years later, Gustav Kirchhoff and Robert Bunsen [7] noticed that several Fraunhofer lines coincide with characteristic emission lines identified in the spectra of heated chemical elements. [8] They inferred that dark lines in the solar spectrum are caused by absorption by chemical elements in the solar atmosphere. [9]