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Fluoroalcohol. 3 languages. 日本語 ... Printable version; In other projects ... [1] Perfluoroalcohols. Most primary and secondary perfluoroalcohols are unstable, ...
The synthesis of fluorotelomer alcohols requires a varying number of tetrafluoroethylene monomers that form an oligomer with a pentafluoroethyl iodide telogen. The fluorinated iodide then undergoes an addition with ethylene to form an organoiodine compound with increased synthesis possibilities. [ 1 ]
Hexafluoro-propan-2-ol is a speciality solvent for organic synthesis, particularly for reactions involving oxidations and strong electrophiles. For example, HFIP enhances the reactivity of hydrogen peroxide as applied to Baeyer-Villiger oxidation of cyclic ketones. [ 1 ]
2-Fluoroethanol was originally synthesized by treating 2-chloroethanol with potassium fluoride, in a simple Finkelstein reaction. [5] The product has a lower boiling point that the starting material and may be conveniently isolated by distillation.
Trifluoroacetaldehyde, trifluoroethanal, or fluoral, [2] is a fluorinated derivative of acetaldehyde with the formula CF 3 CHO.It is a gas at room temperature. Fluoral is used to introduce trifluoromethyl groups into organic compounds.
Nonafluoro-tert-butyl alcohol (IUPAC name: 1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol) is a fluoroalcohol. It is the perfluorinated analog of tert -butyl alcohol . Notably, as a consequence of its electron withdrawing fluorine substituents, it is very acidic for an alcohol, with a p K a value of 5.4, similar to that of a carboxylic acid.
In this process, chain growth is optimized to produce alcohols with narrow molecular weight distribution. Synthesis of other alcohols use Ziegler and the updated EPAL process, such as the transalkylation of styrene to form 2-phenylethanol. Diethylaluminum hydride can be employed in place of triethylaluminium. [1]
Fluorination with aminosulfuranes is a chemical reaction that transforms oxidized organic compounds into organofluorine compounds.Aminosulfuranes selectively exchange hydroxyl groups for fluorine, but are also capable of converting carbonyl groups, halides, silyl ethers, and other functionality into organofluorides.