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While Robin continues to evade the government agents from capturing her, Luffy uses his Haki techniques to defeat Fake Luffy's group. Meanwhile, the government agents capture the Fake Robin. Sanji learns about what has happened to Zoro from a fisherman. While talking to the fisherman, Sanji finally discovers Zoro as he destroys the ship he was in.
Luffy says that the Haki users there are him, Law, Zoro and Sanji. The marines are continuing their fight against Caesar's men. The three centaurs open the door and see a big glop of Slime that seeps out poison gas, most of them die and two survive so they run as it chases them.
The remaining 4 episodes give insight into the fates of Luffy's crew, while Luffy with Hancock's help, who fell in love with him, travels to Impel Down, the world's largest prison, to save his adoptive older brother, Portgas D. Ace, from execution. The season initially ran from July 5 through October 11, 2009 on Fuji Television in Japan.
Luffy attempt to fight back using Armament Haki, but his punches go right though him, much to Luffy's confusion, as Trebol question Luffy's assumption of his Devil Fruit being a Logia. Law tells Luffy that fighting Trebol is futile, while revealing Trebol's slime is in fact mucus, before he begins to insult Trebol and the other executives.
Rayleigh teaches Luffy two Haki techniques, using the first technique, Observation Haki (a power feeling a person's presence) to avoid the elephant's attack. Rayleigh then knocks out the elephant with Armament Haki (another technique used as an invisible shield and can render a Logia-type Devil Fruit user unconscious).
However, Zoro manages to bring the Haki back into his arm. Hitetsu explains that the Enma is considered impossible to wield because it always uses excessive amounts of the wielder's Haki. Still, Zoro to keep the blade. Luffy continues training his Armament Haki and Zoro trains with his new sword.
Upon reaching Luffy, Katakuri transforms back into his human body as he enlarges one of his forarms while covering it flaming Armament Haki-imbued spikes, and he slams it into Luffy in a move called Buzz Cut Mochi. In addition to being injured, Luffy becomes stuck to the club, and Katakuri spins it around rapidly before slamming it into the ...
Luffy, Usopp, Chopper and Franky are at first disappointed upon seeing the ninja but instantly change their minds after he shows off his impressive ninja skills. Meanwhile Robin investigates an unusual red Ponegliff lying within the chamber. After she finishes deciphering it she discovers coordinates to an unknown location.