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In general terms, the free energy change (ΔG) of a reaction determines whether a chemical change will take place, but kinetics describes how fast the reaction is. A reaction can be very exothermic and have a very positive entropy change but will not happen in practice if the reaction
Iron rusting has a low reaction rate. This process is slow. Wood combustion has a high reaction rate. This process is fast. The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. [1]
Stopped-flow spectrometry enables the solution-phase study of chemical kinetics for fast reactions, typically with half-lives in the millisecond range. Initially, it was primarily used for investigating enzyme-catalyzed reactions but quickly became a staple in biochemistry, biophysics, and chemistry laboratories for tracking rapid chemical ...
Regardless, this reaction is still very useful as it has notably fast reaction kinetics. [ 36 ] The applications of this reaction include labeling proteins containing serine as the first residue: the serine is oxidized to aldehyde with NaIO 4 and then converted to nitrone with p-methoxybenzenethiol, N-methylhydroxylamine and p-ansidine, and ...
Examples are those involving catalysis and enzymatic reactions. Heterogeneous reactions where reactants are in different phases are also candidates for diffusion control. One classical test for diffusion control of a heterogeneous reaction is to observe whether the rate of reaction is affected by stirring or agitation; if so then the reaction ...
Thermodynamic control is obtained, however the reaction remains incomplete unless the product enolate is trapped, as in the example below. Since H transfers are very fast, the trapping reaction being slower, the ratio of trapped products largely mirrors the deprotonation equilibrium.
“In principle automatic controls will always do a better job than a human operator because they don’t get tired or distracted, have very fast reactions and have as many eyes and other sensors ...
Pseudocapacitance originates from a coupled, reversible redox reaction with several oxidation steps with overlapping potential. The electrons mostly come from the electrode's valence orbitals. The electron transfer reaction is very fast and can be accompanied with high currents. The electron transfer reaction takes place according to: