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ASR can lead to serious cracking in concrete, resulting in critical structural problems that can even force the demolition of a particular structure. [4] [5] [6] The expansion of concrete through reaction between cement and aggregates was first studied by Thomas E. Stanton in California during the 1930s with his founding publication in 1940. [7]
Radiolarite is a siliceous, comparatively hard, fine-grained, chert-like, and homogeneous sedimentary rock that is composed predominantly of the microscopic remains of radiolarians. This term is also used for indurated radiolarian oozes and sometimes as a synonym of radiolarian earth.
900 to 1050 °C – the remaining calcium carbonate decomposes to calcium oxide (CaO) and CO 2. 1300 to 1450 °C – partial (20–30%) melting takes place, and belite reacts with calcium oxide to form alite (Ca 3 O·SiO 4) (also known as C3S in the Cement Industry). Typical clinker nodules. Alite is the characteristic constituent of Portland ...
When atmospheric carbon dioxide (CO 2), or carbonate ions (HCO − 3, CO 2− 3 dissolved in water) diffuse into concrete from its external surface, they react with calcium hydroxide (portlandite, Ca(OH) 2) and the pH of the concrete pore water progressively decreases from 13.5 – 12.5 to 8.5 (pH of water in equilibrium with calcite).
It is used as a sealant in roads or on the shells of fresh eggs: when sodium silicate is applied as a sealant to cured concrete or egg shells, it chemically reacts with calcium hydroxide or calcium carbonate to form calcium silicate hydrate, sealing micropores with a relatively impermeable material. [16] [17]
A carbonate is a salt of carbonic acid, (H 2 CO 3), [2] characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO 2− 3. The word "carbonate" may also refer to a carbonate ester , an organic compound containing the carbonate group O=C(−O−) 2 .
A fairly well-defined reaction front can often be observed in thin sections; ahead of the front the concrete is normal, or near normal. Behind the reaction front, the composition and the microstructure of concrete are modified. These changes may vary in type or severity but commonly include: Extensive cracking; Expansion
Natural pozzolana (volcanic ash) deposits situated in Southern California in the United States. Pozzolans are a broad class of siliceous and aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH) 2) at ordinary temperature to form compounds possessing ...