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The Mollier enthalpy–entropy diagram for water and steam. The "dryness fraction", x , gives the fraction by mass of gaseous water in the wet region, the remainder being droplets of liquid. An enthalpy–entropy chart , also known as the H – S chart or Mollier diagram , plots the total heat against entropy, [ 1 ] describing the enthalpy of a ...
For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
The heat content of an ideal gas is independent of pressure (or volume), but the heat content of real gases varies with pressure, hence the need to define the state for the gas (real or ideal) and the pressure. Note that for some thermodynamic databases such as for steam, the reference temperature is 273.15 K (0 °C).
If the gas is heated so that the temperature of the gas goes up to T 2 while the piston is allowed to rise to V 2 as in Figure 1, then the pressure is kept the same in this process due to the free floating piston being allowed to rise making the process an isobaric process or constant pressure process. This Process Path is a straight horizontal ...
For a gas, it is the hypothetical state the gas would assume if it obeyed the ideal gas equation at a pressure of 1 bar. For a gaseous or solid solute present in a diluted ideal solution , the standard state is the hypothetical state of concentration of the solute of exactly one mole per liter (1 M ) at a pressure of 1 bar extrapolated from ...
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
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A similar concept applies to liquid–gas phase changes. [7] Water is an exception which has a solid-liquid boundary with negative slope so that the melting point decreases with pressure. This occurs because ice (solid water) is less dense than liquid water, as shown by the fact that ice floats on water.