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This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Positive azeotropes are also called minimum boiling mixtures or pressure maximum azeotropes. A well-known example of a positive azeotrope is an ethanol –water mixture (obtained by fermentation of sugars) consisting of 95.63% ethanol and 4.37% water (by mass), which boils at 78.2 °C. [ 10 ]
Stability of residue curves in the vicinity of binary azeotropes. Pure components and azeotropic points are called nodes. Three different types are possible: Stable node: This is the pure component or the azeotropic point with the highest boiling temperature and lowest vapor pressure in a distillation region. All residue curves end at stable nodes.
The Dortmund Data Bank [1] (short DDB) is a factual data bank for thermodynamic and thermophysical data. Its main usage is the data supply for process simulation where experimental data are the basis for the design, analysis, synthesis, and optimization of chemical processes.
Phase diagram (left) and process flow diagram (right) of an apparatus for the azeotropic distillation with "material separation agent". In this case the phase diagram includes a zone where components are not miscible, so following the condensation of the azeotrope, it is possible to separate the liquid components through decantation.
The table is sortable by each of the following refrigerant properties (scroll right or reduce magnification to view more properties): Type/prefix (see legends) ASHRAE number; IUPAC chemical name; molecular formula; CAS registry number / blend name; Atmospheric lifetime in years; Semi-empirical ozone depletion potential, ODP (normalized to be 1 ...
VCCLAB partition coefficient log P, solubility, data format conversion, molecular descriptors; PubChem online molecule editor that supports SMILES/SMARTS, InChI, and all common chemical file formats
It is characterized by an azeotrope temperature and an azeotropic composition, often expressed as a mole fraction. There can be maximum-boiling azeotropes, where the azeotrope temperature is at a maximum in the boiling curves, or minimum-boiling azeotropes, where the azeotrope temperature is at a minimum in the boiling curves.