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The spin transition is an example of transition between two electronic states in molecular chemistry. The ability of an electron to transit from a stable to another stable (or metastable ) electronic state in a reversible and detectable fashion, makes these molecular systems appealing in the field of molecular electronics .
In quantum physics, Fermi's golden rule is a formula that describes the transition rate (the probability of a transition per unit time) from one energy eigenstate of a quantum system to a group of energy eigenstates in a continuum, as a result of a weak perturbation.
In physics and chemistry, a selection rule, or transition rule, formally constrains the possible transitions of a system from one quantum state to another. Selection rules have been derived for electromagnetic transitions in molecules , in atoms , in atomic nuclei , and so on.
Schematic equal-time spin correlation functions for ferromagnetic and antiferromagnetic materials both above and below versus the distance normalized by the correlation length, . In all cases, correlations are strongest nearest to the origin, indicating that a spin has the strongest influence on its nearest neighbors.
The spin magnetic moment of the electron is =, where is the spin (or intrinsic angular-momentum) vector, is the Bohr magneton, and = is the electron-spin g-factor. Here μ {\displaystyle {\boldsymbol {\mu }}} is a negative constant multiplied by the spin , so the spin magnetic moment is antiparallel to the spin.
In atomic physics and quantum chemistry, Hund's rules refers to a set of rules that German physicist Friedrich Hund formulated around 1925, which are used to determine the term symbol that corresponds to the ground state of a multi-electron atom. The first rule is especially important in chemistry, where it is often referred to simply as Hund's ...
The superscript three (read as triplet) indicates that the multiplicity 2S+1 = 3, so that the total spin S = 1. This spin is due to two unpaired electrons, as a result of Hund's rule which favors the single filling of degenerate orbitals. The triplet consists of three states with spin components +1, 0 and –1 along the direction of the total ...
The conventional definition of the spin quantum number is s = n / 2 , where n can be any non-negative integer. Hence the allowed values of s are 0, 1 / 2 , 1, 3 / 2 , 2, etc. The value of s for an elementary particle depends only on the type of particle and cannot be altered in any known way (in contrast to the spin ...