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BTA is a weak acid with a pK a = 8.2 [3] [4] It is a very weak Brønsted base with pK a < 0. [4] Not only can it act either as an acid or base, it can also bind to other species, utilizing the lone pair electrons. Applying this property, the BTA can form a stable coordination compound on a copper surface and behave as a corrosion inhibitor. [6]
The effectiveness of a corrosion inhibitor depends on fluid composition and dynamics. Corrosion inhibitors are common in industry, and also found in over-the-counter products, typically in spray form in combination with a lubricant and sometimes a penetrating oil. They may be added to water to prevent leaching of lead or copper from pipes. [2]
The prevention and removal of surface dirt and corrosion products are the primary concerns of conservator-restorers when dealing with copper or copper-alloy objects. Perseus with the Head of Medusa , bronze, by Benvenuto Cellini, in the Loggia dei Lanzi gallery on the edge of the Piazza della Signoria in Florence; picture taken after the statue ...
Pickling is a metal surface treatment used to remove impurities, such as stains, inorganic contaminants, and rust or scale from ferrous metals, copper, precious metals and aluminium alloys. [1] A solution called pickle liquor , which usually contains acid , is used to remove the surface impurities.
The mechanism for copper begins the same as for steel, evolution of the inhibitor. Once at the copper surface however, the inhibitor will form a copper benzotriazole complex which is protective. [9] Vapor pressure is a critical parameter in VCI effectiveness. The most favorable range of pressure is 10 −3 to 10 −2 Pa at room temperature ...
Anaerobic corrosion is evident as layers of metal sulfides and hydrogen sulfide smell. On cast iron, a graphitic corrosion selective leaching may be the result, with iron being consumed by the bacteria, leaving graphite matrix with low mechanical strength in place. Various corrosion inhibitors can be used to
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