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Olefin Conversion Technology, also called the Phillips Triolefin Process, is the industrial process that interconverts propylene with ethylene and 2-butenes. [1] The process is also called the ethylene to propylene (ETP) process. In ETP, ethylene is dimerized to 1-butene, which is isomerized to 2-butenes.
Generally, the choice of method is governed by the raw material and energy situations as well as by the availability of oxygen at a reasonable price. In general, 100 parts of ethene gives: 95 parts acetaldehyde; 1.9 parts chlorinated aldehydes; 1.1 parts unconverted ethene; 0.8 parts carbon dioxide; 0.7 parts acetic acid; 0.1 parts chloromethane
For example, CH 3-CH 3 is the alkane ethANe. The name of CH 2 =CH 2 is therefore ethENe. For straight-chain alkenes with 4 or more carbon atoms, that name does not completely identify the compound. For those cases, and for branched acyclic alkenes, the following rules apply: Find the longest carbon chain in the molecule.
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
Structure of (acac)Rh(C 2 H 4)(C 2 F 4), distances (red) in picometers. [3]The bonding between alkenes and transition metals is described by the Dewar–Chatt–Duncanson model, which involves donation of electrons in the pi-orbital on the alkene to empty orbitals on the metal.
A 3D model of ethyne (), the simplest alkyneIn organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. [1] The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula C n H 2n−2.
Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula C 2 H 4 or H 2 C=CH 2. It is a colourless, flammable gas with a faint "sweet and musky " odour when pure. [ 7 ] It is the simplest alkene (a hydrocarbon with carbon–carbon double bonds ).
Usually Ziegler catalysts refer to titanium-based systems for conversions of ethylene and Ziegler–Natta catalysts refer to systems for conversions of propylene. Also, in the 1960s, BASF developed a gas-phase, mechanically-stirred polymerization process for making polypropylene. In that process, the particle bed in the reactor was either not ...