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The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
The Lee–Kesler method [1] allows the estimation of the saturated vapor pressure at a given temperature for all components for which the critical pressure P c, the critical temperature T c, and the acentric factor ω are known.
Data in the table above is given for water–steam equilibria at various temperatures over the entire temperature range at which liquid water can exist. Pressure of the equilibrium is given in the second column in kPa. The third column is the heat content of each gram of the liquid phase relative to water at 0 °C.
The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure ... Water 8.14019: 1810.94: 244 ...
An example is the azeotrope of approximately 95% ethanol and water. Because the azeotrope's vapor pressure is higher than predicted by Raoult's law, it boils at a temperature below that of either pure component. There are also systems with negative deviations that have vapor pressures that are lower than expected.
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According to Sazonov and Shaw, [7] the dimensionless Bunsen coefficient is defined as "the volume of saturating gas, V1, reduced to T° = 273.15 K, p° = 1 bar, which is absorbed by unit volume V 2 * of pure solvent at the temperature of measurement and partial pressure of 1 bar."