enow.com Web Search

Search results

  1. Results from the WOW.Com Content Network
  2. SNi - Wikipedia

    en.wikipedia.org/wiki/SNi

    With standard S N 1 reaction conditions the reaction outcome is retention via a competing S N i mechanism and not racemization and with pyridine added the result is again inversion. [5] [3] S N i reaction mechanism Sn1 occurs in tertiary carbon while Sn2 occurs in primary carbon

  3. SN1 reaction - Wikipedia

    en.wikipedia.org/wiki/SN1_reaction

    General reaction scheme for the S N 1 reaction. The leaving group is denoted "X", and the nucleophile is denoted "Nu–H". The unimolecular nucleophilic substitution (S N 1) reaction is a substitution reaction in organic chemistry.

  4. Sigmatropic reaction - Wikipedia

    en.wikipedia.org/wiki/Sigmatropic_reaction

    Sigmatropic rearrangements are concisely described by an order term [i,j], which is defined as the migration of a σ-bond adjacent to one or more π systems to a new position (i−1) and (j−1) atoms removed from the original location of the σ-bond. [3]

  5. Substitution reaction - Wikipedia

    en.wikipedia.org/wiki/Substitution_reaction

    A more detailed explanation of this can be found in the main SN1 reaction page. S N 2 reaction mechanism. The S N 2 mechanism has just one step. The attack of the reagent and the expulsion of the leaving group happen simultaneously. This mechanism always results in inversion of configuration.

  6. Walden inversion - Wikipedia

    en.wikipedia.org/wiki/Walden_inversion

    In the Walden inversion, the backside attack by the nucleophile in an S N 2 reaction gives rise to a product whose configuration is opposite to the reactant. Therefore, during S N 2 reaction, 100% inversion of product takes place. This is known as Walden inversion. It was first observed by chemist Paul Walden in 1896.

  7. Nucleic acid metabolism - Wikipedia

    en.wikipedia.org/wiki/Nucleic_acid_metabolism

    Nucleic acid metabolism is a collective term that refers to the variety of chemical reactions by which nucleic acids (DNA and/or RNA) are either synthesized or degraded.. Nucleic acids are polymers (so-called "biopolymers") made up of a variety of monomers called nucleo

  8. Molecular Structure of Nucleic Acids: A Structure for ...

    en.wikipedia.org/wiki/Molecular_Structure_of...

    The two base-pair complementary chains of the DNA molecule allow replication of the genetic instructions. The "specific pairing" is a key feature of the Watson and Crick model of DNA, the pairing of nucleotide subunits. [5] In DNA, the amount of guanine is equal to cytosine and the amount of adenine is equal to thymine. The A:T and C:G pairs ...

  9. Racemization - Wikipedia

    en.wikipedia.org/wiki/Racemization

    In chemistry, racemization is a conversion, by heat or by chemical reaction, of an optically active compound into a racemic (optically inactive) form. This creates a 1:1 molar ratio of enantiomers and is referred to as a racemic mixture (i.e. contain equal amount of (+) and (−) forms).