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Lewis dot structure of a Hydroxide ion compared to a hydroxyl radical. In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1] [2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most ...
The hydroxyl radical • OH combines with H 2 S to form HS • and water. [21] Other reactions investigated by Tiee (1981) are HS • + ethylene, HS • + O 2 → HO • + SO, and reactions with itself HS • + HS • → H 2 S 2 or H 2 and S. [22] The disulfide can further react with HS • to make the disulfide radical HS–S • and H 2 S. [19]
A trivalent group 14 radical (also known as a trivalent tetrel radical) is a molecule that contains a group 14 element (E = C, Si, Ge, Sn, Pb) with three bonds and a free radical, having the general formula of R 3 E•. Such compounds can be categorized into three different types, depending on the structure (or equivalently the orbital in which ...
The hydroxyl radical can damage virtually all types of macromolecules: carbohydrates, nucleic acids , lipids (lipid peroxidation) and amino acids (e.g. conversion of Phe to m-Tyrosine and o-Tyrosine). The hydroxyl radical has a very short in vivo half-life of approximately 10 −9 seconds and a high reactivity. [5]
Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into other things such as atoms, ions, or radicals, usually in a reversible manner.
In organic chemistry, an alkyl group is an alkane missing one hydrogen. [1] The term alkyl is intentionally unspecific to include many possible substitutions. An acyclic alkyl has the general formula of −C n H 2n+1. A cycloalkyl group is derived from a cycloalkane by removal of a hydrogen atom from a ring and has the general formula −C n H ...
The hydroperoxyl radical, also known as the hydrogen superoxide, is the protonated form of superoxide with the chemical formula HO 2, also written HOO •. This species plays an important role in the atmosphere and as a reactive oxygen species in cell biology.
In organic chemistry, a radical-substitution reaction is a substitution reaction involving free radicals as a reactive intermediate. [1] The reaction always involves at least two steps, and possibly a third. In the first step called initiation (2,3), a free radical is created by homolysis.