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A uranate is a ternary oxide involving the element uranium in one of the oxidation states 4, 5 or 6. A typical chemical formula is M x U y O z , where M represents a cation. The uranium atom in uranates(VI) has two short collinear U–O bonds and either four or six more next nearest oxygen atoms. [ 1 ]
Sodium uranate may be obtained in the amorphous form by heating together urano-uranic oxide and sodium chlorate; or by heating sodium uranyl acetate or carbonate. The crystalline form is produced by adding the green oxide in small quantities to fused sodium chloride, or by dissolving the amorphous form in fused sodium chloride, and allowing ...
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Ammonium diuranate or (ADU) ((NH 4) 2 U 2 O 7), is one of the intermediate chemical forms of uranium produced during yellowcake production. The name "yellowcake" originally given to this bright yellow salt, now applies to mixtures of uranium oxides which are actually hardly ever yellow.
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The compositions were variable and depended upon the leachant and subsequent precipitating conditions. The compounds identified in yellowcakes include uranyl hydroxide, uranyl sulfate, sodium para-uranate, and uranyl peroxide, along with various uranium oxides. Modern yellowcake typically contains 70% to 90% triuranium octoxide (U 3 O 8) by weight.
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