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[1] [2] [3] It can also be synthesized as a side product of the dehydration of 2-methylcyclohexanol into 1-methylcyclohexene. Structure
Hydration reaction mechanism from 1-methylcyclohexene to 1-methylcyclohexanol. Many alternative routes are available for producing alcohols, including the hydroboration–oxidation reaction , the oxymercuration–reduction reaction , the Mukaiyama hydration , the reduction of ketones and aldehydes and as a biological method fermentation .
Methylcyclohexene can refer to any of three compounds: 1-Methylcyclohexene; 3-Methylcyclohexene; 4-Methylcyclohexene This page was last edited on 18 November ...
Professor David Todd at Pomona College was testing the dehydration of 2-methylcyclohexanol or 4-methylcyclohexanol c. 1994 and unexpectedly interrupted the alkene distillation midway to have lunch with his secretary, Evelyn Jacoby. After lunch, he continued his distillation but kept the early products separate from the completed ones.
Most methylcyclohexane is extracted from petroleum but it can be also produced by catalytic hydrogenation of toluene: CH 3 C 6 H 5 + 3 H 2 → CH 3 C 6 H 11. Methylcyclohexane, as a component of a mixture, is usually dehydrogenated to toluene, which increases the octane rating of gasoline.
Oxidation of 1-methylcyclohexene catalyzed by cytochrome P450 yields a 2:1 mixture of hydroxylation to epoxidation products. [4] The stereochemistry of hydroformylation has been examined using 1-methylcyclohexene. The main product has the formyl group on the less substituted alkene-carbon, trans with respect to the methyl substituent.
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Cyclohexylmethanol is an organic compound with the formula C 6 H 11 −CH 2 −OH. It is a cyclohexane ring functionalized with an alcohol , specifically a hydroxymethyl group. The compound is a colorless liquid, although commercial samples can appear yellow.