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The Wigner–Seitz radius, named after Eugene Wigner and Frederick Seitz, is the radius of a sphere whose volume is equal to the mean volume per atom in a solid (for first group metals). [1] In the more general case of metals having more valence electrons, r s {\displaystyle r_{\rm {s}}} is the radius of a sphere whose volume is equal to the ...
The surface-area-to-volume ratio has physical dimension inverse length (L −1) and is therefore expressed in units of inverse metre (m-1) or its prefixed unit multiples and submultiples. As an example, a cube with sides of length 1 cm will have a surface area of 6 cm 2 and a volume of 1 cm 3. The surface to volume ratio for this cube is thus
In applied sciences, the equivalent radius (or mean radius) is the radius of a circle or sphere with the same perimeter, area, or volume of a non-circular or non-spherical object. The equivalent diameter (or mean diameter ) ( D {\displaystyle D} ) is twice the equivalent radius.
The van der Waals radius, r w, of an atom is the radius of an imaginary hard sphere representing the distance of closest approach for another atom. It is named after Johannes Diderik van der Waals, winner of the 1910 Nobel Prize in Physics, as he was the first to recognise that atoms were not simply points and to demonstrate the physical consequences of their size through the van der Waals ...
Once the radius is fixed, the three coordinates (r, θ, φ), known as a 3-tuple, provide a coordinate system on a sphere, typically called the spherical polar coordinates. The plane passing through the origin and perpendicular to the polar axis (where the polar angle is a right angle ) is called the reference plane (sometimes fundamental plane ).
The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
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Using the number density as a function of spatial coordinates, the total number of objects N in the entire volume V can be calculated as = (,,), where dV = dx dy dz is a volume element. If each object possesses the same mass m 0 , the total mass m of all the objects in the volume V can be expressed as m = ∭ V m 0 n ( x , y , z ) d V ...