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Boric acid in equilibrium with its conjugate base the borate ion is widely used (in the concentration range 50–100 ppm boron equivalents) as a primary or adjunct pH buffer system in swimming pools. Boric acid is a weak acid, with p K a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of ...
Borax is also easily converted to boric acid and other borates, which have many applications. Its reaction with hydrochloric acid to form boric acid is: Na 2 B 4 O 7 ·10H 2 O + 2 HCl → 4 H 3 BO 3 + 2 NaCl + 5 H 2 O. Borax is sufficiently stable to find use as a primary standard for acid-base titrimetry. [17]: p.316
Borate concentration (giving buffering capacity) can vary from 10 mM to 100 mM. As BBS is used to emulate physiological conditions (as in animal or human body), the pH value is slightly alkaline, ranging from 8.0 to 9.0. NaCl gives the isotonic (mostly used 150 mM NaCl corresponds to physiological conditions: 0.9% NaCl) salt concentration.
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
In animals, boric acid/borate salts are essentially completely absorbed following oral ingestion. Absorption occurs via inhalation, although quantitative data are unavailable. Limited data indicate that boric acid/salts are not absorbed through intact skin to any significant extent, although absorption occurs through skin that is severely abraded.
Download as PDF; Printable version; In other projects ... This page provides supplementary chemical data on boric acid . Thermodynamic properties. Phase behavior ...
Note that in solution H + exists as the hydronium ion H 3 O +, and further aquation of the hydronium ion has negligible effect on the dissociation equilibrium, except at very high acid concentration. Figure 2. Buffer capacity β for a 0.1 M solution of a weak acid with a pK a = 7
Total boron is an important quantity when determining alkalinity due to borate's contribution to a solution's acid neutraling capacity. Total boron is a conservative element in seawater, and can thus be calculated by simply knowing the salinity.