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Bromopentanes are a group of bromoalkanes consisting of pentane isomers with one or more hydrogen atoms replaced by bromine atoms. They have the formula C 5 H 12–n Br n, where n = 1–12 is the number of bromine atoms. They are colorless liquids.
3-Bromopentane is a bromoalkane and isomer of bromopentane. It is a colorless liquid. References This page was last edited on 27 February 2024, at 20:34 (UTC). Text ...
Enantiotopic groups are identical and indistinguishable except in chiral environments. For instance, the CH 2 hydrogens in ethanol (CH 3 CH 2 OH) are normally enantiotopic, but can be made different (diastereotopic) if combined with a chiral center, for instance by conversion to an ester of a chiral carboxylic acid such as lactic acid, or if coordinated to a chiral metal center, or if ...
2-Bromopentane is a bromoalkane and isomer of bromopentane. It is a colorless liquid. 2-Bromopentane is chiral and thus can be obtained as either of two stereoisomers designated as ( R )-2-bromopentane and ( S )-2-bromopentane, or as a racemic 1:1 mixture of the two enantiomers .
It uses hydrogen donor compounds such as formic acid, isopropanol or dihydroanthracene, dehydrogenating them to CO 2, acetone, or anthracene respectively. [1] Often, the donor molecules also function as solvents for the reaction. A large scale application of transfer hydrogenation is coal liquefaction using "donor solvents" such as tetralin. [2 ...
Formic acid and formate salts may also be used as reductants in transfer hydrogenations. Simple aryl ketones are reduced enantioselectively when a chiral amino alcohol ligand is employed. [4] (9) Transition metal catalysts have also been used with hydrogen gas as the stoichiometric reductant.
Most side reactions occur due to the Lewis-acidity of the byproduct, ZnI 2. In reactions that produce acid-sensitive products, excess Et 2 Zn can be added to scavenge the ZnI 2 that is formed, forming the less acidic EtZnI. The reaction can also be quenched with pyridine, which will scavenge ZnI 2 and excess reagents. [24]
An odd number is an indication of the involvement of a charged C atom or of a heteroatom lone pair replacing a CC double bond. Thus, [1,5] and [3,3] shifts become [1,4] and [2,3] shifts with heteroatoms, while preserving symmetry considerations. Hydrogens are omitted in the third example for clarity.