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  2. Capillary electrochromatography - Wikipedia

    en.wikipedia.org/.../Capillary_electrochromatography

    In chemical analysis, capillary electrochromatography (CEC) is a chromatographic technique in which the mobile phase is driven through the chromatographic bed by electro-osmosis. [1] [2] Capillary electrochromatography is a combination of two analytical techniques, high-performance liquid chromatography and capillary electrophoresis.

  3. Capillary length - Wikipedia

    en.wikipedia.org/wiki/Capillary_length

    The capillary length will vary for different liquids and different conditions. Here is a picture of a water droplet on a lotus leaf. If the temperature is 20 o then = 2.71mm . The capillary length or capillary constant is a length scaling factor that relates gravity and surface tension.

  4. Electrochromatography - Wikipedia

    en.wikipedia.org/wiki/Electrochromatography

    Capillary electrochromatography (CEC) is an electrochromatography technique in which the liquid mobile phase is driven through a capillary containing the chromatographic stationary phase by electroosmosis. [3] [4] It is a combination of high-performance liquid chromatography and capillary electrophoresis. The capillaries is packed with HPLC ...

  5. Chromatography - Wikipedia

    en.wikipedia.org/wiki/Chromatography

    Liquid chromatography (LC) is a separation technique in which the mobile phase is a liquid. It can be carried out either in a column or a plane. Present day liquid chromatography that generally utilizes very small packing particles and a relatively high pressure is referred to as high-performance liquid chromatography.

  6. Capillary electrophoresis - Wikipedia

    en.wikipedia.org/wiki/Capillary_electrophoresis

    Capillary electrophoresis (CE) is a family of electrokinetic separation methods performed in submillimeter diameter capillaries and in micro- and nanofluidic channels.Very often, CE refers to capillary zone electrophoresis (CZE), but other electrophoretic techniques including capillary gel electrophoresis (CGE), capillary isoelectric focusing (CIEF), capillary isotachophoresis and micellar ...

  7. Van Deemter equation - Wikipedia

    en.wikipedia.org/wiki/Van_Deemter_equation

    In liquid chromatography, the mobile phase velocity is taken as the exit velocity, that is, the ratio of the flow rate in ml/second to the cross-sectional area of the ‘column-exit flow path.’ For a packed column, the cross-sectional area of the column exit flow path is usually taken as 0.6 times the cross-sectional area of the column.

  8. High-performance liquid chromatography - Wikipedia

    en.wikipedia.org/wiki/High-performance_liquid...

    HPLC is distinguished from traditional ("low pressure") liquid chromatography because operational pressures are significantly higher (around 50–1400 bar), while ordinary liquid chromatography typically relies on the force of gravity to pass the mobile phase through the packed column. Due to the small sample amount separated in analytical HPLC ...

  9. Electroextraction - Wikipedia

    en.wikipedia.org/wiki/Electroextraction

    The outlet of the capillary is then grounded. [8] When EE is coupled to isotachophoresis coupled to capillary electrophoresis, limits of detection decrease to the nanomolar range and isotachophoresis takes only a few minutes to complete. Similar limits of detections are obtained when EE is coupled to liquid chromatography-mass spectrometry. [1]

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