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For example, Cp′Fe(PPh 3)(CO)I has four different signals in the 1 H NMR spectrum for the ring hydrogens and five different signals in the 13 C NMR spectrum for the ring carbons. There is therefore no symmetry within the ring even accounting for rotation around the ring–metal axis, but instead there is a diastereotopic relationship as a ...
2,3-pentadiene, H 3 C−CH=C=CH−CH 3, with two enantiomers (R and S). [5] It and 1,2-pentadiene are the least common isomers of pentadiene. Well known derivatives containing pentadiene groups include hexadienes , cyclopentadiene , and especially three fatty acids linoleic acid , α- linolenic acid , and arachidonic acid as well as their ...
NiCl 2 + 2 NaC 5 H 5 → Ni(C 5 H 5) 2 + 2 NaCl Organometallic complexes that include both the cyclopentadienyl anion and cyclopentadiene itself are known, one example of which is the rhodocene derivative produced from the rhodocene monomer in protic solvents .
Di-tert-butylcyclopentadiene is an organic compound with the formula (Me 3 C) 2 C 5 H 4, where Me = methyl.It is a colorless liquid that is soluble in organic solvents. The compound is the conjugate acid of the di-tert-butylcyclopentadienyl ligand, (Me 3 C) 2 C 5 H 3 − [1] (sometimes abbreviated Cp ‡−).
1,2,3,4,5-Pentakis(4-butylphenyl)-1,3-cyclopentadiene is an organochemical compound from the diene group and a cyclopentadiene derivative. The anion of this compound is used as a sterically demanding ligand, often abbreviated as Cp [BIG] , in the organometallic chemistry of sandwich compounds .
2 t Bu − 3. These ligands are so large that their complexes behave differently from the pentamethylcyclopentadienyl analogues. Because they cannot closely approach the metal, these bulky ligands stabilize high spin complexes, such as (C 5 H 2 t Bu 3) 2 Fe 2 I 2. These large ligands stabilize highly unsaturated derivatives such as (C 5 H 2 t ...
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Typical examples of this type of complex are group 14 metal complexes such as CpSiMe 3. An example of both is (Cp 2 Fe(CO) 2). It is probable that η 1-Cp complexes are intermediates in the formation of η 5-Cp complexes. Still rarer, the Cp unit can bond to the metal via three carbons. In these η 3-Cp complexes, the bonding resembles that in ...