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In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole moment, with a negatively charged end and a positively charged end. Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms.
Electronegativity. Electrostatic potential map of a water molecule, where the oxygen atom has a more negative charge (red) than the positive (blue) hydrogen atoms. Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. [1]
Covalent bond. A covalent bond forming H 2 (right) where two hydrogen atoms share the two electrons. A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms ...
Electronegativity (Pauling scale) → Atomic radius decreases → Ionization energy increases → Electronegativity increases →. There are no reliable sources for Pm, Eu and Yb other than the range of 1.1–1.2; see Pauling, Linus (1960). The Nature of the Chemical Bond. 3rd ed., Cornell University Press, p. 93.
Carbon–hydrogen bond. In chemistry, the carbon-hydrogen bond (C−H bond) is a chemical bond between carbon and hydrogen atoms that can be found in many organic compounds. [1] This bond is a covalent, single bond, meaning that carbon shares its outer valence electrons with up to four hydrogens. This completes both of their outer shells ...
The electronegativity difference between the elements is therefore 1.54. Because of this moderately large difference in electronegativities, the Si−O bond is polar but not fully ionic . Carbon has an electronegativity of 2.55 so carbon–oxygen bonds have an electronegativity difference of 0.89 and are less polar than silicon–oxygen bonds.
The high electronegativity of fluorine (4.0 for fluorine vs. 2.5 for carbon) gives the carbon–fluorine bond a significant polarity or dipole moment. The electron density is concentrated around the fluorine, leaving the carbon relatively electron poor. This introduces ionic character to the bond through partial charges (C δ+ —F δ−). The ...
Carbon–oxygen bond. A carbon–oxygen bond is a polar covalent bond between atoms of carbon and oxygen. [1][2][3]: 16–22 Carbon–oxygen bonds are found in many inorganic compounds such as carbon oxides and oxohalides, carbonates and metal carbonyls, [4] and in organic compounds such as alcohols, ethers, and carbonyl compounds. [5]: 32–36 ...